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The O-H bond length in methanol is

  • A.109 pm
  • B.136 pm
  • C.96 pm
  • D.141 pm
  • E.142 pm

Answer: C

The O-H bond length in methanol is 96 pm.

In methanol the oxygen is sp3 hybridised. The textbook structure gives the O-H bond as 96 pm and the C-O bond as 142 pm, with a C-O-H angle of 108.9°. The O-H bond is short because hydrogen is a very small atom.

142 pm and 141 pm are close to the C-O bond length, and 136 pm is close to the C-O bond in phenol. 109 pm is a typical C-H bond length. None of these is the O-H bond.

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