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In hydrogen spectrum, the shortest wavelength of Bracket series is produced during the transition between the states

  • A.\(n_{2} = 5\) and \(n_{1} = 4\)
  • B.\(n_{2} = 4\) and \(n_{1} = 1\)
  • C.\(n_{2} = 4\) and \(n_{1} = 3\)
  • D.\(n_{2} = \infty\) and \(n_{1} = 4\)
  • E.\(n_{2} = 4\) and \(n_{1} = 2\)

Answer: D

The transition is \(n_{2} = \infty\) and \(n_{1} = 4\).

The Brackett series consists of transitions ending on n = 4. Its wavelengths satisfy \(\frac{1}{\lambda} = R\left(\frac{1}{4^{2}} - \frac{1}{n_{2}^{2}}\right)\). The shortest wavelength means the largest energy gap, which is from \(n_{2} = \infty\), the series limit.

5 to 4 is the longest wavelength of the Brackett series. Transitions ending on n = 1, 2 or 3 belong to the Lyman, Balmer and Paschen series.

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