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Assertion (A): Reaction calorimetry is used before scaling up an exothermic batch process.
Reason (R): It measures the rate of heat release, which can then be compared with the plant cooling capacity.

  • A.Both A and R are true, and R is the correct explanation of A
  • B.Both A and R are true, but R is not the correct explanation of A
  • C.A is true but R is false
  • D.A is false but R is true

Answer: A

Correct answer: Both A and R are true, and R is the correct explanation of A

Both are true and the reason gives the purpose. A reaction calorimeter measures the heat release rate against time on a laboratory scale, and that curve can be compared directly with what the plant vessel’s jacket can remove - which the scaling item shows will be proportionally less. If the peak release exceeds the cooling, the process must be changed to semi-batch, diluted or run cooler before it goes anywhere near a plant.

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