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In a gas chromatograph :

(i) FID uses an oxygen rich flame
(ii) FPD uses a hydrogen rich flame

  • A.(i) is correct (ii) is wrong
  • B.(i) is wrong (ii) is correct
  • C.(i) and (ii) both are correct
  • D.(i) and (ii) both are wrong

Answer: C

The answer is (i) and (ii) both are correct.

A flame ionisation detector burns hydrogen in an excess of air, a lean, oxygen-rich flame in which organic compounds are burnt completely and form ions that are measured as a current. A flame photometric detector uses a hydrogen-rich flame, which reduces sulphur and phosphorus compounds to excited species (S2* and HPO*) that emit light at characteristic wavelengths.

Since both descriptions are accurate, the options marking either one wrong, or both, are incorrect.

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