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Which carrier gas gives the flattest van Deemter curve?

  • A.Carbon dioxide
  • B.Hydrogen
  • C.Nitrogen
  • D.Argon

Answer: B

Hydrogen has the highest diffusivity, which both lowers the mass transfer term and flattens the curve, so a column can be run well above its optimum with little loss of efficiency and a much shorter analysis. Nitrogen gives the lowest minimum but a sharp curve, and helium sits between. Flatness matters more than depth when speed is wanted, which is why hydrogen has displaced helium wherever its flammability can be managed. A limit that survives making every external component ideal is an intrinsic one, and worth knowing for that reason.

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