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The adsorbent which has higher adsorptive power in column chromatography is :

  • A.\(\mathrm{SiO}_{2}\)
  • B.MgO
  • C.\(\mathrm{CaCO}_{3}\)
  • D.\(\mathrm{Al}_{2}\mathrm{O}_{3}\)

Answer: D

The adsorbent with the higher adsorptive power is Al2O3.

In column chromatography the common adsorbents are ranked by their activity (adsorbing strength). Activated alumina is the strongest of those listed: its surface has Lewis-acidic aluminium sites and hydroxyl groups that hold polar compounds firmly. Silica gel is a little weaker and is the most widely used general adsorbent. Magnesium oxide is weaker still, and calcium carbonate is a weak adsorbent used for very sensitive compounds such as some plant pigments.

So, in the standard order of decreasing activity, alumina comes ahead of silica, magnesia and calcium carbonate.

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