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Quantum confinement occurs when a particle's size becomes comparable to the

  • A.wavelength of visible light
  • B.spacing of its crystal lattice
  • C.mean free path of a gas molecule at that pressure
  • D.wavelength of its charge carriers

Answer: D

Correct answer: wavelength of its charge carriers

When the particle becomes comparable with the de Broglie wavelength of its electrons and holes - the exciton Bohr radius - the carriers are squeezed and their energy levels become discrete and size-dependent. This is why a quantum dot’s band gap, and so its emission colour, can be tuned simply by changing its diameter.

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