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A nylon-6,6 chain of number average mass 22 600, with a repeat unit of 226, has a degree of polymerisation of

  • A.22 600
  • B.100
  • C.1000
  • D.10

Answer: B

Correct answer: 100

Dividing as before,

\[ DP = \frac{22\,600}{226} = 100 \]

so a hundred repeat units, each comprising one adipic acid and one hexamethylenediamine residue. Note that a nylon repeat unit is much heavier than an ethylene one, so a similar molecular mass corresponds to a far shorter chain.

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