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What is the relation between wavelength and wavenumber?

  • A.Wavenumber is proportional to the square of wavelength
  • B.Wavenumber is the wavelength expressed in micrometres
  • C.Wavenumber is the reciprocal of wavelength
  • D.Wavenumber is the wavelength divided by the speed of light

Answer: C

Wavenumber is one over the wavelength, conventionally in reciprocal centimetres, so it is directly proportional to photon energy. Dividing by the speed of light gives a time, there is no square relation, and micrometres are just another length unit. Infrared work uses wavenumbers precisely because a scale linear in energy makes vibrational transitions evenly spaced, while ultraviolet and visible work keeps nanometres. Checking the units of each quantity catches a wrong formula before the arithmetic begins.

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