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Which one of the following statements regarding moisture sorption isotherms of a dried food is NOT correct?

  • A.At a given temperature, the difference between adsorption and desorption moisture isotherms is known as hysteresis.
  • B.At a given temperature and water activity, an adsorption isotherm exhibits higher equilibrium moisture content than a desorption isotherm in hysteresis.
  • C.At a given moisture content, effect of temperature on a moisture sorption isotherm follows the Clausius-Clapeyron equation.
  • D.The Guggenheim-Anderson-de Boer (GAB) equation is a multilayer moisture sorption model.

Answer: B

The statement that is NOT correct is an adsorption isotherm exhibits higher equilibrium moisture content than a desorption isotherm in hysteresis.

In sorption hysteresis it is the other way round: at the same temperature and water activity, the desorption isotherm lies above the adsorption isotherm, so a food being dried holds more water than the same food rewetted to that activity.

The other statements are correct. The gap between the two curves is what hysteresis means; at constant moisture content, the temperature dependence of water activity follows the Clausius-Clapeyron equation through the isosteric heat of sorption; and the GAB equation is a three-parameter multilayer model extending BET.

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