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GATE CH 2023: Chemical Engineering

  • Paper code: CH
  • Language: English
  • 42 pages
GATE CH 2023 question paper, GATE 2023, Chemical Engineering, page 1 of 42
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Chemical Engineering (CH)


General Aptitude (GA)
Q.1 – Q.5 Carry ONE mark Each

 Q.1       “You are delaying the completion of the task. Send _______ contributions at the
           earliest.”




 (A)       you are


 (B)       your


 (C)       you’re


 (D)       yore




 Q.2       References : ______ : : Guidelines : Implement

           (By word meaning)




 (A)       Sight


 (B)       Site


 (C)       Cite


 (D)       Plagiarise




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Chemical Engineering (CH)



 Q.3       In the given figure, PQRS is a parallelogram with PS = 7 cm, PT = 4 cm and
           PV = 5 cm. What is the length of RS in cm? (The diagram is representative.)

                                                      7
                                   P                                    S

                                                      5     90°
                                           4
                                               90°                  V
                         Q             T                        R


 (A)       20
            7

 (B)       28
            5

 (C)       9
           2

 (D)       35
            4




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Chemical Engineering (CH)



 Q.4       In 2022, June Huh was awarded the Fields medal, which is the highest prize in
           Mathematics.

           When he was younger, he was also a poet. He did not win any medals in the
           International Mathematics Olympiads. He dropped out of college.

           Based only on the above information, which one of the following statements can be
           logically inferred with certainty?




 (A)       Every Fields medalist has won a medal in an International Mathematics Olympiad.


 (B)       Everyone who has dropped out of college has won the Fields medal.


 (C)       All Fields medalists are part-time poets.


 (D)       Some Fields medalists have dropped out of college.




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Chemical Engineering (CH)



 Q.5       A line of symmetry is defined as a line that divides a figure into two parts in a way
           such that each part is a mirror image of the other part about that line.

           The given figure consists of 16 unit squares arranged as shown. In addition to the
           three black squares, what is the minimum number of squares that must be coloured
           black, such that both PQ and MN form lines of symmetry? (The figure is
           representative)

                                              P                  N




                         M
                                              Q

 (A)       3


 (B)       4


 (C)       5


 (D)       6




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Chemical Engineering (CH)


Q.6 – Q.10 Carry TWO marks Each

 Q.6       Human beings are one among many creatures that inhabit an imagined world. In
           this imagined world, some creatures are cruel. If in this imagined world, it is given
           that the statement “Some human beings are not cruel creatures” is FALSE, then
           which of the following set of statement(s) can be logically inferred with certainty?

                 (i)     All human beings are cruel creatures.
                 (ii)    Some human beings are cruel creatures.
                 (iii)   Some creatures that are cruel are human beings.
                 (iv)    No human beings are cruel creatures.




 (A)       only (i)


 (B)       only (iii) and (iv)


 (C)       only (i) and (ii)


 (D)       (i), (ii) and (iii)




 Q.7       To construct a wall, sand and cement are mixed in the ratio of 3:1. The cost of sand
           and that of cement are in the ratio of 1:2.

           If the total cost of sand and cement to construct the wall is 1000 rupees, then what
           is the cost (in rupees) of cement used?




 (A)       400


 (B)       600


 (C)       800


 (D)       200


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Chemical Engineering (CH)


           The World Bank has declared that it does not plan to offer new financing to Sri
 Q.8       Lanka, which is battling its worst economic crisis in decades, until the country has
           an adequate macroeconomic policy framework in place. In a statement, the World
           Bank said Sri Lanka needed to adopt structural reforms that focus on economic
           stabilisation and tackle the root causes of its crisis. The latter has starved it of
           foreign exchange and led to shortages of food, fuel, and medicines. The bank is
           repurposing resources under existing loans to help alleviate shortages of essential
           items such as medicine, cooking gas, fertiliser, meals for children, and cash for
           vulnerable households.

           Based only on the above passage, which one of the following statements can be
           inferred with certainty?




 (A)       According to the World Bank, the root cause of Sri Lanka’s economic crisis is that
           it does not have enough foreign exchange.


 (B)       The World Bank has stated that it will advise the Sri Lankan government about how
           to tackle the root causes of its economic crisis.


 (C)       According to the World Bank, Sri Lanka does not yet have an adequate
           macroeconomic policy framework.


 (D)       The World Bank has stated that it will provide Sri Lanka with additional funds for
           essentials such as food, fuel, and medicines.




 Q.9       The coefficient of x 4 in the polynomial (x − 1)3 (x − 2)3 is equal to _______.




 (A)       33


 (B)       ̶ 3


 (C)       30


 (D)       21


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Chemical Engineering (CH)



 Q.10      Which one of the following shapes can be used to tile (completely cover by
           repeating) a flat plane, extending to infinity in all directions, without leaving any
           empty spaces in between them? The copies of the shape used to tile are identical
           and are not allowed to overlap.




 (A)       circle


 (B)       regular octagon


 (C)       regular pentagon


 (D)       rhombus




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Chemical Engineering (CH)


Q.11 – Q.35 Carry ONE mark Each

 Q.11      Which one of the following is the CORRECT value of y, as defined by the
           expression given below?


                                                  2x
                                         y = lim x
                                             x→0 e − 1

 (A)       1


 (B)       2


 (C)       0


 (D)       ∞




 Q.12      The vector ⃗v is defined as

                                   ⃗v = zx î + 2xy ĵ + 3yz k̂ .
           Which one of the following is the CORRECT value of divergence of ⃗v, evaluated
           at the point (x, y, z) = (3, 2, 1) ?




 (A)       0


 (B)       3


 (C)       14


 (D)       13



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Chemical Engineering (CH)



 Q.13      Given that

                                        |z1 + z2 |
                                    F=               ,
                                       |z1 | + |z2 |
           where z1 = 2 + 3i and z2 = −2 + 3i with i = √−1 , which one of the
           following options is CORRECT?




 (A)
           F<0

 (B)       F<1

 (C)       F>1

 (D)       F=1




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Chemical Engineering (CH)



 Q.14      For a two-dimensional plane, the unit vectors, (êr , êθ ) of the polar coordinate
           system and (î, ĵ) of the cartesian coordinate system, are related by the following two
           equations.

                                      êr = cosθ î + sinθ ĵ
                                      êθ = −sinθ î + cosθ ĵ
                                                                      ∂(êr +ê θ )
           Which one of the following is the CORRECT value of                         ?
                                                                           ∂θ




 (A)       1

 (B)       êθ

 (C)       êr + êθ

 (D)       −êr + êθ




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Chemical Engineering (CH)



 Q.15      Which one of the following statements related to octane number is NOT correct?




 (A)       Linear alkanes with higher carbon number have higher octane number.


 (B)       Branching in linear alkanes increases their octane number.


 (C)       Catalytic reforming of hydrocarbons increases their octane number.


 (D)       Gasoline quality is measured in terms of octane number.




 Q.16      Which one of the following options represents the major components of oleum?




 (A)       Sulfuric acid and nitric acid


 (B)       Concentrated sulfuric acid and petroleum jelly


 (C)       Sulfuric acid and hydrochloric acid


 (D)       Sulfuric acid and sulfur trioxide




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Chemical Engineering (CH)



 Q.17      For a reversible endothermic chemical reaction with constant heat of reaction over
           the operating temperature range, K is the thermodynamic equilibrium constant.
           Which one of the following figures shows the CORRECT dependence of K on
           temperature T?




 (A)




 (B)




 (C)




 (D)




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 Q.18      Nitrile rubber is manufactured via polymerization process. Which one of the
           following options is the CORRECT pair of monomers used in this process?




 (A)       Acrylonitrile and styrene


 (B)       Acrylonitrile and butadiene


 (C)       Butadiene and styrene


 (D)       Butadiene and isoprene




 Q.19      John and Jane independently performed a thermodynamic experiment, in which X
           and Y represent the initial and final thermodynamic states of the system,
           respectively. John performed the experiment under reversible conditions, for which
           the change in entropy of the system was ΔSrev . Jane performed the experiment
           under irreversible conditions, for which the change in entropy of the system was
           ΔSirr . Which one of the following relationships is CORRECT?




 (A)       ΔSrev = ΔSirr

 (B)       ΔSrev > ΔSirr

 (C)       ΔSrev < ΔSirr

 (D)       ΔSrev = 2ΔSirr




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 Q.20      For a packed-bed comprising of uniform-sized spherical particles of diameter Dp ,
           the pressure drop across the bed is given by the Kozeny-Carman equation when the
           particle Reynolds number (Rep ) < 1. Under this condition, minimum fluidization
           velocity is proportional to Dpn . Which one of the following is the CORRECT value
           of exponent n ?




 (A)       2


 (B)       −1


 (C)       −2


 (D)       1




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 Q.21      Match the quantities in Group 1 with their units in Group 2 listed in the table below.




                                     Group 1                              Group 2


                    P) Thermal conductivity                       I)     W. m−2 K −1


                    Q) Convective heat transfer coefficient       II)    W. m−1 K −1


                    R) Stefan-Boltzmann constant                  III)   W. K −1


                    S) Heat capacity rate                         IV)    W. m−2 K −4




 (A)       P-II, Q-I, R-IV, S-III


 (B)       P-I, Q-II, R-III, S-IV


 (C)       P-III, Q-IV, R-II, S-I


 (D)       P-IV, Q-I, R-III, S-II




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Chemical Engineering (CH)



 Q.22      A slab of thickness L, as shown in the figure below, has cross-sectional area A and
           constant thermal conductivity k. T1 and T2 are the temperatures at x = 0 and
           x = L, respectively. Which one of the following options is the CORRECT
           expression of the thermal resistance for steady-state one-dimensional heat
           conduction?




 (A)        L
           kA

 (B)       k
           LA

 (C)       kA(T1 −T2 )
                 L

 (D)       A
           Lk




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Chemical Engineering (CH)



 Q.23      Spray dryers have many advantages. Which one of the following is NOT an
           advantage of a typical spray dryer?




 (A)       Has short drying time


 (B)       Produces hollow spherical particles


 (C)       Has high heat efficiency


 (D)       Is suitable for heat sensitive materials




 Q.24      Which one of the following quantities of a flowing fluid is measured using a
           rotameter?




 (A)       Static pressure


 (B)       Dynamic pressure


 (C)       Volumetric flow rate


 (D)       Viscosity




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Chemical Engineering (CH)



 Q.25      A liquid surge tank has Fin and Fout as the inlet and outlet flow rates respectively,
           as shown in the figure below. Fout is proportional to the square root of the liquid
           level ℎ. The cross-sectional area of the tank is 20 cm2 . Density of the liquid is
           constant everywhere in the system. At steady state, Fin = Fout = 10 cm3 s−1 and
           ℎ = 16 cm. The variation of ℎ with Fin is approximated as a first order transfer
           function. Which one of the following is the CORRECT value of the time constant
           (in seconds) of this system?




 (A)       20


 (B)       32


 (C)       64


 (D)       128




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Chemical Engineering (CH)



 Q.26      A packed distillation column, with vapor having an average molecular weight of
           45 kg. kmol−1, density of 2 kg. m−3 and a molar flow rate of 0.1 kmol. s −1, has a
           flooding velocity of 0.15 m. s−1 . The column is designed to operate at 60 % of the
           flooding velocity. Which one of the following is the CORRECT value for the
           column diameter (in m)?




 (A)        5
           √π


 (B)       5 √π


 (C)       4π


 (D)       10
           √π




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 Q.27      An isothermal jacketed continous stirred tank reactor (CSTR) operating at 150 o C
           is shown in the figure below. The cold feed entering the system at 30 o C is preheated
           to a temperature T (T < 150 o C) using a heat exchanger HX1 . This preheated feed
           is further heated to 150 o C using the utility heater HX2. The mass flow rate and heat
           capacity are same for all the process streams, and the overall heat transfer
           coefficient is independent of temperature. Which one of the following statements is
           the CORRECT action to take if it is desired to increase the value of T ?




 (A)       Increase both heat transfer area of HX1 and heat duty of HX2.


 (B)       Decrease both heat transfer area of HX1 and heat duty of HX2 .


 (C)       Increase the heat transfer area of HX1 and decrease the heat duty of HX2.


 (D)       Decrease the heat transfer area of HX1 and increase the heat duty of HX2 .




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 Q.28      Consider a system where a Carnot engine is operating between a source and a sink.
           Which of the following statements about this system is/are NOT correct?




 (A)       This engine is reversible.


 (B)       The engine efficiency is independent of the source and sink temperatures.


 (C)       This engine has the highest efficiency among all engines that operate between the
           same source and sink.


 (D)       The total entropy of this system increases at the completion of each cycle of the
           engine.




 Q.29      For a fully developed turbulent flow of an incompressible Newtonian fluid through
           a pipe of constant diameter, which of the following statements is/are CORRECT?




 (A)       Reynolds stress, averaged over a sufficiently long time, is zero everywhere inside
           the pipe.


 (B)       Reynolds stress at the pipe wall is zero.


 (C)       Average velocity of the fluid is half of its center-line velocity.


 (D)       Average pressure gradient in the flow direction is constant.




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Chemical Engineering (CH)



 Q.30      Given that E (in W. m−2 ) is the total hemispherical emissive power of a surface
           maintained at a certain temperature, which of the following statements is/are
           CORRECT?




 (A)       E does not depend on the direction of the emission.


 (B)       E depends on the viewfactor.


 (C)       E depends on the wavelength of the emission.


 (D)       E does not depend on the frequency of the emission.




 Q.31      The position x(t) of a particle, at constant ω, is described by the equation

                                           d2 x
                                                  = −ω2 x .
                                           dt 2
                                                            dx
           The initial conditions are x(t = 0) = 1 and           |     = 0. The position of the
                                                            dt t=0

           particle at t = (3 π/ω) is __________ (in integer).




 Q.32      Burning of methane in a combustor yields carbon monoxide, carbon dioxide, and
           water vapor. Methane is fed to the combustor at 100 mol. hr −1 , of which 50 %
           reacts. The theoretical oxygen requirement (in mol. hr −1 ) is ________ (rounded off
           to one decimal place).




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 Q.33      The viscosity of an incompressible Newtonian fluid is measured using a capillary
           tube of diameter 0.5 mm and length 1.5 m. The fluid flow is laminar, steady and
           fully developed. For a flow rate of 1 cm3 s −1 , the pressure drop across the length of
           the tube is 1 MPa. If the viscosity of the fluid is k × 10−3 Pa. s, the value of k is
           ___________ (rounded off to two decimal places).




 Q.34      A liquid L containing a dissolved gas S is stripped in a countercurrent operation
           using a pure carrier gas V. The liquid phase inlet and outlet mole fractions of S are
           0.1 and 0.01, respectively. The equilibrium distribution of S between V and L is
           governed by ye = xe , where ye and xe are the mole fractions of S in V and L,
           respectively. The molar feed rate of the carrier gas stream is twice as that of the
           liquid stream. Under dilute solution conditions, the minimum number of ideal stages
           required is __________ (in integer).




 Q.35      In a binary gas-liquid system, NA,EMD is the molar flux of a gas A for equimolar
           counter diffusion with a liquid B. NA,UMD is the molar flux of A for steady one-
           component diffusion through stagnant B. Using the mole fraction of A in the bulk
           of the gas phase as 0.2 and that at the gas-liquid interface as 0.1 for both the modes
           of diffusion, the ratio of NA,UMD to NA,EMD is equal to ______ (rounded off to two
           decimal places).




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Q.36 – Q.65 Carry TWO marks Each

 Q.36      An exhibition was held in a hall on 15 August 2022 between 3 PM and 4 PM during
           which any person was allowed to enter only once. Visitors who entered before
           3:40 PM exited the hall exactly after 20 minutes from their time of entry. Visitors
           who entered at or after 3:40 PM, exited exactly at 4 PM. The probability distribution
           of the arrival time of any visitor is uniform between 3 PM and 4 PM. Two persons
           X and Y entered the exhibition hall independent of each other. Which one of the
           following values is the probability that their visits to the exhibition overlapped with
           each other?




 (A)       5
           9

 (B)       4
           9

 (C)       2
           9

 (D)       7
           9




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 Q.37      Simpson’s one-third rule is used to estimate the definite integral

                                               1
                                      I = ∫ √(1 − x 2 )dx
                                              −1

           with an interval length of 0.5. Which one of the following is the CORRECT
           estimate of I obtained using this rule?




 (A)       1   1
             −
           3 √3


 (B)       1   2
             +
           3 √3


 (C)       1   1
             +
           3 √3


 (D)       1   2
             −
           3 √3




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 Q.38      Match the products in Group 1 with the manufacturing processes in Group 2 listed
           in the table below.




                                   Group 1                        Group 2


                        P)   Acetaldehyde              I)    Sulfate process


                        Q) Sulfuric acid               II)   Electric furnace process


                        R) Pulp                        III) Wacker process


                        S) Phosphorus                  IV) Contact process



 (A)       P-III, Q-IV, R-I, S-II


 (B)       P-III, Q-I, R-IV, S-II


 (C)       P-IV, Q-I, R-II, S-III


 (D)       P-I, Q-IV, R-II, S-III




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 Q.39      Match the reactions in Group 1 with the catalysts in Group 2 listed in the table
           below.




                                    Group 1                                 Group 2

                                                                      I) Mixed oxide
                                                                         of Mo and Fe


                                                                      II) V2 O5


                                                                      III) FeCl3



                                                                      IV) Ag 2 O




 (A)       P-III, Q-IV, R-II, S-I


 (B)       P-III, Q-IV, R-I, S-II


 (C)       P-IV, Q-II, R-I, S-III


 (D)       P-IV, Q-III, R-I, S-II




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 Q.40      Water in a container at 290 K is exposed to air containing 3 % CO2 by volume. Air
           behaves like an ideal gas and is maintained at 100 kPa pressure. The liquid phase
           comprising of dissolved CO2 in water behaves like an ideal solution. Use Henry’s
           constant of CO2 dissolved in water at 290 K as 12 MPa. Under equilibrium
           conditions, which one of the following is the CORRECT value of the mole fraction
           of CO2 dissolved in water?




 (A)       2.9 × 10−4

 (B)       0.9 × 10−4

 (C)       2.5 × 10−4

 (D)       0.5 × 10−4




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 Q.41      The enthalpy (H, in J. mol−1 ) of a binary liquid system at constant temperature and
           pressure is given as

                              H = 40x1 + 60x2 + x1 x2 (4x1 + 2x2 ) ,


           where x1 and x2 represent the mole fractions of species 1 and 2 in the liquid,
           respectively. Which one of the following is the CORRECT value of the partial
                                                               ∞
           molar enthalpy of species 1 at infinite dilution, H1 (in J. mol−1 ) ?




 (A)       100


 (B)       42


 (C)       64


 (D)       40




 Q.42      Which one of the following represents the CORRECT effects of concentration
           polarization in a reverse osmosis process?




 (A)       Reduced water flux and reduced solute rejection


 (B)       Increased water flux and increased solute rejection


 (C)       Reduced water flux and increased solute rejection


 (D)       Increased water flux and reduced solute rejection




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 Q.43      CO and H2 participate in a catalytic reaction. The partial pressures (in atm) of the
           reacting species CO and H2 in the feed stream are pCO and pH2 , respectively. While
           CO undergoes molecular adsorption, H2 adsorbs via dissociative adsorption, that is,
           as hydrogen atoms. The equilibrium constants (in atm−1 ) corresponding to
           adsorption of CO and H2 to the catalyst sites are KCO and KH 2 , respectively. Total
           molar concentration of active sites per unit mass of the catalyst is Ct (in
           mol. (g cat)−1). Both the adsorption steps are at equilibrium. Which one of the
           following expressions is the CORRECT ratio of the concentration of catalyst sites
           occupied by CO to that by hydrogen atoms?




 (A)




 (B)




 (C)




 (D)




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 Q.44      A cascade control strategy is shown in the figure below. The transfer function
           between the output (y) and the secondary disturbance (d2 ) is defined as

                                                   y(s)
                                      Gd2 (s) =           .
                                                   d2 (s)

           Which one of the following is the CORRECT expression for the transfer function
           Gd2 (s) ?




 (A)                   1
           (11s+21)(0.1s+1)


 (B)               1
           (s+1)(0.1s+1)


 (C)            (s+1)
           (s+2)(0.1s+1)


 (D)            (s+1)
           (s+1)(0.1s+1)




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 Q.45      Level (ℎ) in a steam boiler is controlled by manipulating the flow rate (F) of the
           make-up (fresh) water using a proportional (P) controller. The transfer function
           between the output and the manipulated input is

                                      ℎ(s) 0.25(1 − s)
                                           =           .
                                      F(s)   s(2s + 1)
           The measurement and valve transfer functions are both equal to 1. A process
           engineer wants to tune the controller so that the closed-loop response gives decaying
           oscillations under servo mode. Which one of the following is the CORRECT value
           of the controller gain to be used by the engineer?




 (A)       0.25


 (B)       2


 (C)       4


 (D)       6




 Q.46      Which of the following statements is/are CORRECT?




 (A)       Bond number includes surface tension.


 (B)       Jakob number includes latent heat.


 (C)       Prandtl number includes liquid-vapor density difference.


 (D)       Biot number includes gravity.



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Chemical Engineering (CH)



 Q.47      If a matrix M is defined as M = [10       6 ], the sum of all the eigenvalues of M3 is
                                                6    10
           equal to __________ (in integer).




 Q.48      The first derivative of the function

                                                 1 12  1 6
                                      U(r) = 4 [( ) − ( ) ]
                                                 r     r
           evaluated at r = 1 is ______ (in integer).




 Q.49      Wet air containing 10 mole percent water vapor is dried by continuously passing it
           through a column of CaCl2 pellets. The pellets remove 50 percent of water from wet
           air entering the column. The mole percent of water vapor in the product stream
           exiting the column is ___________ (rounded off to two decimal places).




 Q.50      Orsat analysis showing the composition (in mol %, on a dry basis) of a stack gas is
           given in the table below. The humidity measurement reveals that the mole fraction
           of H2 O in the stack gas is 0.07. The mole fraction of N2 calculated on a wet basis
           is ________ (rounded off to two decimal places).



                                   Species          N2       CO2   CO    O2


                                   mol %            65       15    10    10




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Chemical Engineering (CH)



 Q.51      A pump draws water (density = 1000 kg. m−3 ) at a steady rate of 10 kg. s −1 . The
           pressures at the suction and discharge sides of the pump are −20 kPa (gauge) and
           350 kPa (gauge), respectively. The pipe diameters at the suction and discharge side
           are 70 mm and 50 mm, respectively. The suction and discharge lines are at the
           same elevation, and the pump operates at an efficiency of 80 %. Neglecting
           frictional losses in the system, the power (in kW) required to drive the pump is
           ______ (rounded off to two decimal places).




 Q.52      A cylindrical tank with a diameter of 500 mm contains water (density = 1 g. cm−3)
           upto a height ℎ. A 5 mm diameter round nozzle, whose center is 1 cm above the
           base of the tank, has its exit open to the atmosphere as shown in the schematic
           below. The pressure above the water level in the tank is maintained at
           2 bar (absolute). Neglect all frictional and entry/exit losses. Use acceleration due
           to gravity as 10 m. s −2 and atmospheric pressure as 1 bar. The absolute value of
                     dℎ
           initial        (in mm. s−1) when ℎ = 51 cm is equal to ________ (rounded off to two
                     dt
           decimal places).




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Chemical Engineering (CH)



 Q.53      A large tank is filled with water (density = 1 g. cm−3 ) upto a height of 5 m. A
           100 μm diameter solid spherical particle (density = 0.8 g. cm−3) is released at the
           bottom of the tank. The particle attains its terminal velocity (vt ) after traveling to a
           certain height in the tank. Use acceleration due to gravity as 10 m. s −2 and water
           viscosity as 10−3 Pa. s . Neglect wall effects on the particle. If Stokes law is
           applicable, the absolute value of vt (in mm. s −1 ) is ____________(rounded off to
           two decimal places).




 Q.54      A fluid is flowing steadily under laminar conditions over a thin rectangular plate at
           temperature Ts as shown in the figure below. The velocity and temperature of the
           free stream are u∞ and T∞ , respectively. When the fluid flow is only in the x-
           direction, ℎx is the local heat transfer coefficient. Similarly, when the fluid flow is
           only in the y-direction, ℎy is the corresponding local heat transfer coefficient. Use
           the correlation Nu = 0.332 (Re)1/2 (Pr)1/3 for the local heat transfer coefficient,
           where, Nu, Re, and Pr, respectively are the appropriate Nusselt, Reynolds and
           Prandtl numbers. The average heat transfer coefficients are defined as
                   1 l                          1 w
           ℎ̅l = ∫0 ℎx dx and ℎ̅w = ∫0 ℎy dy. If w = 1 m and l = 4 m, the
                   l                            w
                                 ̅     ̅
           value of the ratio of ℎw to ℎl is _______ (in integer).




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Chemical Engineering (CH)



 Q.55      A perfectly insulated, concentric tube countercurrent heat exchanger is used to cool
           lubricating oil using water as a coolant (see figure below). Oil enters the outer
           annulus at a mass flow rate of 2 kg. s−1 with a temperature of 100 o C and leaves at
           40 o C. Water enters the inner tube at a mass flow rate of 1 kg. s −1 with a temperature
           of 20 o C and leaves at 80 o C. Use specific heats of oil and water as 2089 J. kg −1 K −1
           and 4178 J. kg −1 K −1, respectively. There is no phase change in both the streams.
           Under steady-state conditions, the number of transfer units (NTU) is _______ (in
           integer).




 Q.56      Partially saturated air at 1 bar and 50 o C is contacted with water in an adiabatic
           saturator. The air is cooled and humidified to saturation, and exits at 25 o C with an
           absolute humidity of 0.02 kg water per kg dry air. Use latent heat of vaporization
           of water as 2450 kJ. kg −1 , and average specific heat capacity for dry air and water,
           respectively as 1.01 kJ. kg −1 K −1 and 4.18 kJ. kg −1 K −1 . If the absolute humidity of
           air entering the adiabatic saturator is H × 10−3 kg water per kg dry air, the value
           of H is __________ (rounded off to two decimal places).




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Chemical Engineering (CH)



 Q.57      Distillation of a non-reactive binary mixture with components A and B is carried
           out in a batch still as shown in the figure below. The initial charge of the mixture in
           the still is 1 kmol. The initial and final amounts of A in the still are 0.1 kmol and
           0.01 kmol, respectively. Use a constant relative volatility of 4.5. The mole fraction
           of B remaining in the vessel is _______ (rounded off to three decimal places).




 Q.58      Fresh catalyst is loaded into a reactor before the start of the following catalytic
           reaction.



           The catalyst gets deactivated over time. The instantaneous activity a(t), at time t,
           is defined as the ratio of the rate of reaction −rA′ (t) (mol. (g cat)−1 hr −1) to the rate
           of reaction with fresh catalyst. Controlled experimental measurements led to an
           empirical correlation

                                        −rA′ (t) = −0.5t + 10
           where t is in hours. The activity of the catalyst at t = 10 hr is _______ (rounded
           off to one decimal place).




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Chemical Engineering (CH)



 Q.59      A unimolecular, irreversible liquid-phase reaction



           was carried out in an ideal batch reactor at temperature T. The rate of the reaction
           (−rA ) measured at different conversions XA is given in the table below. This
           reaction is also carried out in an ideal continuous stirred tank reactor (CSTR) at the
           same temperature T with a feed concentration of 1 mol. m−3, under steady-state
           conditions. For a conversion of 0.8, the space time (in s) of the CSTR is
           __________ (in integer).




                                   XA         0     0.1    0.2    0.4    0.6    0.8


                       −rA (mol. m−3 s −1 )   0.45 0.35 0.31 0.18 0.11 0.05




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Chemical Engineering (CH)



 Q.60      An irreversible liquid-phase second-order reaction




           with rate constant k = 0.2 liter. mol−1 min−1, is carried out in an isothermal
           non-ideal reactor. A tracer experiment conducted on this reactor resulted in a
           residence time distribution (E-curve) as shown in the figure below. The areas of the
           rectangles (i), (ii), and (iii) are equal. Pure A at a concentration of 1.5 mol. liter −1
           is fed to the reactor. The segregated model mimics the nonideality of this reactor.
           The percentage conversion of A at the exit of the reactor is ______ (rounded off to
           the nearest integer).




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Chemical Engineering (CH)



 Q.61      The outlet concentration CA of a plug flow reactor (PFR) is controlled by
           manipulating the inlet concentration CA0 . The following transfer function describes
           the dynamics of this PFR.

                                   CA (s)            V
                                           = exp [− ( ) (k + s)]
                                   CA0 (s)           F
           In the above equation, V = 1 m3 , F = 0.1 m3 min−1 and k = 0.5 min−1 . The
           measurement and valve transfer functions are both equal to 1. The ultimate gain,
           defined as the proportional controller gain that produces sustained oscillations, for
           this system is ______ (rounded off to one decimal place).




 Q.62      The transfer function of a measuring instrument is

                                                1.05
                                   Gm (s) =           exp(−s) .
                                               2s + 1
           At time t = 0, a step change of +1 unit is introduced in the input of this instrument.
           The time taken by the instrument to show an increase of 1 unit in its output is _____
           (rounded off to two decimal places).




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Chemical Engineering (CH)



 Q.63      A design engineer needs to purchase a membrane module (M) for a plant. Details
           about the two available options, M1 and M2, are given in the table below. The
           overall plant has an expected life of 7 years. If the interest rate is 8 % per annum,
           compounded annually, the difference in the net present value (NPV) of these two
           options, in lakhs of rupees, is ______ (rounded off to one decimal place).




                                                                  M1          M2


                         Purchase cost (in lakhs of rupees)        10          5


                                   Expected life (years)           5           3




 Q.64      The purchase cost of a new distillation column is Rs. 10 lakhs with an installation
           factor of 5.8. The cost of the capital is to be annualized over a period of 6 years at
           a fixed rate of interest of 5 % per annum, compounded annually. The annual cost
           (in lakhs of rupees) of the installed capital is _______ (rounded off to one decimal
           place).




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Chemical Engineering (CH)



 Q.65      Pumps A and B are being considered for purchase in a chemical plant. Cost details
           for these two pumps are given in the table below. The interest rate is 10 % per
           annum, compounded annually. For both the pumps to have the same capitalized
           cost, the salvage value (in Rs.) of pump B should be ______ (rounded off to the
           nearest integer).




               Item                                          Pump A          Pump B


               Installed cost (Rs.)                           16000           32000


               Uniform end of year maintenance (Rs.)          2400             1600


               Salvage value (Rs.)                            1000               ?


               Service life (year(s))                           1                2




                                   END OF QUESTION PAPER




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Source: GATE. Question paper published by GATE.