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Phenol is converted into benzene by heating with

  • A.\(\mathrm{Na / Hg}\)
  • B.\(\mathrm{Zn}\) dust
  • C.\(\mathrm{Cr_{2}O_{3}}\)
  • D.\(\mathrm{LiAlH_{4}}\)
  • E.\(\mathrm{NaBH_{4}}\)

Answer: B

Phenol is converted into benzene by heating with zinc dust.

Zinc dust removes the oxygen of the phenolic group: C6H5OH + Zn → C6H6 + ZnO.

Sodium amalgam, LiAlH4 and NaBH4 are reducing agents for other groups (carbonyl compounds, for example) and do not remove a phenolic –OH. Cr2O3 is a catalyst for aromatisation, not a reagent for this conversion.

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