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Fehling's reagent is a mixture of

  • A.aqueous \(CuSO_{4}\) and ammonical \(AgNO_{3}\) solution
  • B.aqueous \(CuSO_{4}\) and 2,4-DNP
  • C.aqueous KOH and ammonical \(AgNO_{3}\) solution
  • D.aqueous \(CuSO_{4}\) and alkaline sodium potassium tatarate
  • E.aqueous KOH and alkaline sodium potassium tatarate

Answer: D

Fehling's reagent is a mixture of aqueous \(CuSO_{4}\) and alkaline sodium potassium tartrate (printed 'tatarate').

Fehling's solution A is aqueous copper(II) sulphate; Fehling's solution B is alkaline sodium potassium tartrate (Rochelle salt). The tartrate complexes the \(Cu^{2+}\) and keeps it in solution in the alkaline mixture. Aldehydes reduce it to a red-brown precipitate of \(Cu_{2}O\).

Ammoniacal silver nitrate is Tollens' reagent, and 2,4-DNP is a test for carbonyl groups in general, not part of Fehling's reagent. KOH with tartrate alone lacks the copper.

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