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The correct formula of Hinsberg's reagent is

  • A.\(\mathrm{C_{6}H_{5}SO_{2}Cl}\)
  • B.\(\mathrm{C_{6}H_{5}SOCl}\)
  • C.\(\mathrm{C_{6}H_{5}SOCl_{2}}\)
  • D.\(\mathrm{C_{6}H_{5}SO_{3}Cl}\)
  • E.\(\mathrm{C_{6}H_{5}SO_{2}Cl_{2}}\)

Answer: A

Hinsberg's reagent is C6H5SO2Cl, benzenesulphonyl chloride.

It is used to distinguish primary, secondary and tertiary amines: primary amines give a sulphonamide soluble in alkali, secondary amines give one insoluble in alkali, and tertiary amines do not react.

The other formulae do not represent benzenesulphonyl chloride: C6H5SOCl has one oxygen too few, C6H5SO3Cl one too many, and the dichloride formulae carry an extra chlorine.

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