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Consider two non-identical spin \(\frac{1}{2}\) particles labelled 1 and 2 in the spin product state \(|\tfrac{1}{2}, \tfrac{1}{2}\rangle |\tfrac{1}{2}, -\tfrac{1}{2}\rangle\). The Hamiltonian of the system is

\[ H = \frac{4\lambda}{\hbar^{2}}\vec{S}_{1}\cdot\vec{S}_{2} , \]

where \(\vec{S}_{1}\) and \(\vec{S}_{2}\) are the spin operators of particles 1 and 2, respectively, and \(\lambda\) is a constant with appropriate dimensions. What is the expectation value of \(H\) in the above state?

  • A.\(-\lambda\)
  • B.\(-2\lambda\)
  • C.\(\lambda\)
  • D.\(2\lambda\)

Answer: A

The expectation value is \(-\lambda\).

Write the dot product with raising and lowering operators:

\[ \begin{aligned} \vec{S}_{1}\cdot\vec{S}_{2} &= S_{1z}S_{2z} \\ &\quad + \tfrac{1}{2}(S_{1+}S_{2-} + S_{1-}S_{2+}) \end{aligned} \]

In the product state \(|\uparrow\rangle|\downarrow\rangle\), the flip terms turn the state into \(|\downarrow\rangle|\uparrow\rangle\) (or zero), which is orthogonal to it, so their expectation vanishes. Only the \(z\) term survives:

\[ \begin{aligned} \langle H \rangle &= \frac{4\lambda}{\hbar^{2}}\left(\frac{\hbar}{2}\right)\left(-\frac{\hbar}{2}\right) \\ &= -\lambda \end{aligned} \]

\(+\lambda\) is the value for parallel spins (the triplet \(|\uparrow\uparrow\rangle\)). \(-3\lambda\) would be the singlet, and \(\pm 2\lambda\) do not follow from the spin algebra.

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