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What is a hollow cathode lamp made from?

  • A.A tungsten filament in an inert atmosphere
  • B.A deuterium discharge behind a narrow filter
  • C.A quartz envelope containing mercury vapour
  • D.A cathode of the element being determined

Answer: D

The cathode is lined with the analyte metal, so sputtering and excitation produce that element's own emission lines - which is exactly what its atoms in the flame will absorb. A tungsten filament and a deuterium discharge are continuum sources, and mercury vapour would emit mercury's lines. A source built from the analyte itself guarantees a perfect match in wavelength, and the price is one lamp per element. Most errors here come from carrying a result across from a neighbouring case where it does not hold.

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