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Readings drift downward through a long run. What is the most likely cause?

  • A.The burner slot is becoming encrusted with salt
  • B.The lamp is warming and emitting more strongly
  • C.The detector is becoming more sensitive
  • D.The flame temperature is rising steadily

Answer: A

Dissolved solids build up on the burner slot, narrowing it and disturbing the flame, which reduces the number of atoms in the beam. A warming lamp would drift upward if anything, and detector and flame changes are not systematic in this way. Aspirating water between samples and cleaning the slot are the routine remedies, and the drift's direction is what identifies it as a fouling problem rather than an electronic one. Checking the units of each quantity catches a wrong formula before the arithmetic begins.

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