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Two atomisers are compared for the same element.

ParameterFlameFurnace
Detection limit50 ppb0.5 ppb
Sample used5 mL20 uL
Time per sample10 s2 min

Which would suit a large batch of routine samples at 1 ppm?

  • A.Neither, since 1 ppm lies between their ranges
  • B.The flame, for its speed
  • C.The furnace, for its detection limit
  • D.Either, since both reach the level required

Answer: B

At one part per million the flame's fifty parts per billion detection limit is ample, and its ten seconds per sample against two minutes decides a large batch outright. The furnace's sensitivity is simply not needed. Both do reach the level, which is why the third option is tempting, but it ignores the throughput column that the question's word batch points at. Choosing the least capable instrument that meets the requirement is what keeps a laboratory productive.

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