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The variation of steady shear viscosity \((\eta)\) of a polymer melt with shear rate \((\dot{\gamma})\) is shown in the figure, where \(\dot{\gamma}_{s}\) is the upper limit of the applied shear rate.

Log of viscosity against log of shear rate: a flat plateau at low shear rate, then a straight line falling steadily up to the limit gamma dot s

Which one of the following figures, labeled P, Q, R and S, shows the most appropriate variation of shear stress \((\tau)\) with shear rate for the same polymer melt?

Four plots of shear stress against shear rate: P starts flat and curves upward then levels off (S-shaped); Q rises linearly at first then bends over, increasing ever more slowly; R curves upward ever more steeply; S rises, flattens, then rises steeply again

  • A.P
  • B.Q
  • C.R
  • D.S

Answer: B

The right shear stress curve is Q.

The viscosity curve shows a Newtonian plateau at low shear rate, where viscosity is constant, followed by shear thinning, where viscosity falls as a power of the shear rate. Since \(\tau = \eta\dot{\gamma}\):

  • on the plateau, \(\tau\) rises linearly with \(\dot{\gamma}\);
  • in the shear-thinning region, \(\tau = K\dot{\gamma}^{n}\) with n less than 1, so \(\tau\) keeps rising but ever more slowly.

Curve Q, a straight start bending over into a flattening rise, matches. R curves upward, which is shear thickening. P starts with zero slope, which would mean zero viscosity at low shear rate, and S's late steep rise would need the viscosity to increase again, which the viscosity curve does not show.

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