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Discussion

Match each composition unit with what it is a ratio of.
List I
A. Mole fraction
B. Mass fraction
C. Molarity
D. Molality
List II
1. moles of solute to litres of solution
2. moles of a species to total moles
3. moles of solute to kilograms of solvent
4. mass of a species to total mass

  • A.A-3, B-1, C-4, D-2
  • B.A-2, B-4, C-1, D-3
  • C.A-4, B-2, C-1, D-3
  • D.A-2, B-4, C-3, D-1

Answer: B

Correct answer: A-2, B-4, C-1, D-3

Four composition units and four different denominators. Mole fraction is moles of a species over total moles, and mass fraction the same on a mass basis; both are dimensionless and both sum to one over the components. Molarity is moles of solute per litre of *solution*, and molality moles of solute per kilogram of *solvent* - a distinction that matters more than it first appears, as the next item shows.

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