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The structure of B4H10 is given below. Its styx number is

B4H10: two central borons joined by a B-B bond, each with one terminal H; two outer borons, each with two terminal H; each outer boron is linked to each central boron through a bridging H

  • A.4012
  • B.4102
  • C.2104
  • D.2014

Answer: A

The styx number of B4H10 is 4012.

Lipscomb's code counts four kinds of bond: s = B-H-B bridges, t = three-centre B-B-B bonds, y = two-centre B-B bonds, x = extra terminal H beyond one per boron (BH2 groups). From the structure: 4 bridging hydrogens, no closed B-B-B bond, 1 B-B bond between the two central borons, and 2 BH2 groups (the outer borons), so s, t, y, x = 4, 0, 1, 2.

The balance equations for BpHp+q, here p = 4 and q = 6, confirm it:

\[ \begin{aligned} s + x &= q:\ 4 + 2 = 6 \\ s + t &= p:\ 4 + 0 = 4 \\ t + y &= p - q/2:\ 0 + 1 = 1 \end{aligned} \]

4102 swaps t and y, claiming a three-centre bond the arachno structure does not have. 2104 and 2014 count only two bridges, so they fail the balance \(s + t = p\), giving 2 + 1 = 3 and 2 + 0 = 2 instead of 4.

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