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Assertion (A): A supported catalyst uses far less active metal than an unsupported one for the same activity.
Reason (R): Dispersing the metal as small crystallites exposes far more of it as accessible surface.

  • A.A is true but R is false
  • B.A is false but R is true
  • C.Both A and R are true, and R is the correct explanation of A
  • D.Both A and R are true, but R is not the correct explanation of A

Answer: C

Correct answer: Both A and R are true, and R is the correct explanation of A

Both are true and the reason gives the mechanism. Catalysis happens on the surface, so what matters is exposed metal atoms rather than metal mass. Dispersing platinum as crystallites a few nanometres across on a high area support puts a large fraction of the atoms at the surface, where a lump of the same metal would expose a vanishing fraction - which is why a vehicle catalyst uses grams rather than kilograms.

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