Discussion
Which of the following cement compounds is mainly responsible for Initial setting Time of cement ?
Answer: C
Initial setting is mainly due to tri-calcium aluminate (C3A).
C3A reacts with water almost at once and with great heat, and it is this reaction that stiffens the paste first. Left unchecked it causes flash set, which is why gypsum is ground into cement: it slows the C3A reaction enough to leave time for placing.
Tri-calcium silicate (C3S) hydrates next and gives the early strength of the first weeks. Di-calcium silicate (C2S) hydrates slowly and gives later strength. The tetra-calcium compound (C4AF, an aluminoferrite) contributes little to setting or strength.
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