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The number of d-electrons in Fe2+ (Z = 26) is not equal to that of

  • A.p-electrons in Ne (Z = 10)
  • B.s-electrons in Mg (Z = 12)
  • C.d-electrons in Fe (Z = 26)
  • D.p-electrons in Cl (Z = 17)

Answer: D

The odd one out is the p-electrons in Cl (Z = 17).

\(\mathrm{Fe^{2+}}\) is \([\mathrm{Ar}]3d^6\), so it has six d-electrons. Neon \((1s^2 2s^2 2p^6)\) has six p-electrons and magnesium \((1s^2 2s^2 2p^6 3s^2)\) six s-electrons, while neutral Fe is \([\mathrm{Ar}]3d^6 4s^2\) and also has six d-electrons. Chlorine is \(1s^2 2s^2 2p^6 3s^2 3p^5\), giving \(6+5=11\) p-electrons.

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