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What is the structure of IF7 ?

  • A.Trigonal bipyramid
  • B.Pentagonal bipyramid
  • C.Square pyramid
  • D.Tetrahedral

Answer: B

\(\mathrm{IF_7}\) is a pentagonal bipyramid.

Iodine contributes seven bonding pairs and has no lone pair, so by VSEPR the seven pairs arrange themselves as \(sp^3d^3\) - five fluorines in an equatorial plane at 72° and two along the axis. It is one of the few molecules with this geometry.

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