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Which one of the following orders presents the correct sequence of the increasing basic nature of the given oxides?

  • A.K2O < Na2O < MgO < Al2O3
  • B.Al2O3 < MgO < Na2O < K2O
  • C.MgO < Al2O3 < K2O < Na2O
  • D.Na2O < K2O < Al2O3 < MgO

Answer: B

The correct order is \(\mathrm{Al_2O_3 < MgO < Na_2O < K_2O}\).

Basicity of an oxide increases as the element becomes more metallic - that is, down a group and to the left across a period. \(\mathrm{Al_2O_3}\) is amphoteric, MgO weakly basic, and \(\mathrm{Na_2O}\) and \(\mathrm{K_2O}\) strongly basic, with potassium the most electropositive of the four.

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