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Sample of 4 metals A, B, C and D were added to the following solutions separately. The results observed are shown below. What is the order of reactivities of these metals ?

MetalFeSO4CuSO4ZnSO4
ANo changea green deposit-
Ba grey deposita brown depositNo change
C-No change-
Da brown deposit-A white coating on metal

  • A.D \(\lt\) B \(\lt\) A \(\lt\) C
  • B.C \(\lt\) A \(\lt\) D \(\lt\) B
  • C.C \(\lt\) A \(\lt\) B \(\lt\) D
  • D.A \(\lt\) C \(\lt\) B \(\lt\) D

Answer: C

The order of reactivity is C \(\lt\) A \(\lt\) B \(\lt\) D.

A metal displaces a less reactive metal from its salt solution, so a deposit or coating means the added metal is more reactive than the metal in the salt.

  • D displaces zinc from ZnSO4 (white coating) and iron from FeSO4, so it is more reactive than zinc: the most reactive.
  • B displaces iron and copper but not zinc, so it lies between zinc and iron.
  • A does not displace iron but displaces copper, so it lies between iron and copper.
  • C does not even displace copper, so it is the least reactive.

That gives C \(\lt\) A \(\lt\) B \(\lt\) D. The other orders put D below B, or A below C, which contradicts the observed displacements.

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