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The oxygen absorption mechanism of wet corrosion has as its cathodic reaction the reduction of

  • A.oxygen to hydroxyl ions
  • B.hydrogen ions to hydrogen gas
  • C.the metal ions back to the metal
  • D.water to hydrogen and oxygen together

Answer: A

Correct answer: oxygen to hydroxyl ions

In neutral or alkaline solution the cathodic half-reaction is \[ \mathrm{O_2 + 2H_2O + 4e^- \rightarrow 4OH^-}, \] which is why this mechanism is called oxygen absorption. Hydrogen evolution is the competing mechanism and takes over only in acid, where hydrogen ions are plentiful enough to be reduced instead.

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