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A Schottky defect in an ionic crystal is a stochiometric defect of

  • A.Cation vacancy
  • B.Anion vacancy
  • C.Cation and anion vacancy
  • D.Cation and anion interstitial

Answer: C

A Schottky defect is a cation and anion vacancy.

In an ionic crystal such as NaCl, a Schottky defect is a pair (more generally a stoichiometric group) of vacancies: one cation and one anion missing from their lattice sites, the ions having moved to the surface. Removing them in that ratio keeps the crystal electrically neutral and the composition stoichiometric. It lowers the density.

A cation vacancy or an anion vacancy alone would leave a net charge. Interstitial ions belong to the Frenkel defect, in which an ion (usually the smaller cation) leaves its site for an interstitial position, creating a vacancy-interstitial pair.

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