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The electrolyte used in lead storage battery is

  • A.10% \(\mathrm{H_{2}SO_{4}}\) aqueous solution
  • B.60% \(\mathrm{H_{2}SO_{4}}\)aqueous solution
  • C.38% \(\mathrm{H_{2}SO_{4}}\) aqueous solution
  • D.38% HCl aqueous solution
  • E.60% HCl aqueous solution

Answer: C

The electrolyte is 38% H2SO4 aqueous solution.

A lead storage battery has a lead anode and a lead dioxide cathode dipped in sulphuric acid of about 38% by mass (density about 1.3 g mL-1). During discharge both electrodes turn to PbSO4 and the acid is used up, which is why its density is a measure of the state of charge.

Hydrochloric acid is not used, because PbCl2 would form and the cell reactions depend on the sulphate. 10% acid is too dilute and 60% too concentrated for the standard cell.

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