Discussion
Which of the following half-cell reaction has the most negative standard electrode potential?
Answer: A
The most negative standard electrode potential belongs to Li+(aq) + e- → Li(s).
Lithium has the most negative standard reduction potential of all, about -3.05 V, because it loses its electron very readily in water (its small ion is strongly hydrated). It is therefore the strongest reducing agent in aqueous solution.
Na+/Na is also strongly negative (about -2.71 V) but less so than lithium. F2/F- is the most positive of all, about +2.87 V, and I2/I- (about +0.54 V) and Cu+/Cu (about +0.52 V) are positive.
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