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The mass of Al deposited when 2 ampere current is passed through a solution of Al2(SO4)3 for 1 hour is (F = 96500 C)

  • A.0.67 g
  • B.1.34 g
  • C.0.134 g
  • D.0.355 g
  • E.0.067 g

Answer: A

The mass of aluminium deposited is 0.67 g.

The charge passed is \(Q = It\), and each Al3+ ion needs 3 electrons, so 3 F deposit one mole (27 g) of Al.

\[ \begin{aligned} Q &= 2 \times 3600 = 7200 \text{ C} \\ m &= \frac{27 \times 7200}{3 \times 96500} \\ &= \frac{194400}{289500} \approx 0.67 \text{ g} \end{aligned} \]

1.34 g is exactly double the correct mass, and 0.067 g and 0.134 g are factor-of-ten slips; remember that each Al3+ ion takes three electrons.

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