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Sodium is obtained by electrolysis of molten sodium chloride rather than its aqueous solution because in water

  • A.hydrogen would be discharged in preference
  • B.sodium chloride does not dissolve appreciably
  • C.chlorine would not be liberated at the anode
  • D.the solution would not conduct electricity

Answer: A

Water is reduced far more readily than the strongly negative sodium ion, so on most cathodes hydrogen appears instead. The mercury cathode's large hydrogen overvoltage was the exception that made the aqueous route possible.

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