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Assertion: a cell's EMF can be measured accurately with an ordinary low resistance voltmeter. Reason: the EMF is the potential difference between the electrodes.

  • A.both the assertion and the reason are true but the reason does not explain the assertion
  • B.the assertion is true but the reason given for it is false
  • C.the assertion is false although the reason offered is a true statement in itself
  • D.both the assertion and the reason are true and the reason explains the assertion

Answer: C

Correct answer: the assertion is false although the reason offered is a true statement in itself

The reason is a true description of what EMF is, but the assertion fails on the method. A low resistance voltmeter draws appreciable current, and drawing current polarises the electrodes and produces a drop across the internal resistance, so the reading falls below the true EMF. The measurement must be made at essentially zero current - by a potentiometer, or by a modern electrometer of very high input impedance.

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