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One block at temperature \(T_{1}\) and another identical block at temperature \(T_{2}\) are placed in thermal contact and come to an equilibrium, the system being isolated from surroundings. If the heat capacities at constant volume C depend on temperature as C = aT, the entropy change of the system would be :

  • A.\(a\Big[2\Big(\frac{T_{1}^{2}+T_{2}^{2}}{2}\Big)^{1/2}-T_{1}-T_{2}\Big]\)
  • B.\(a\left[\frac{T_{1} + T_{2}}{2}\right]\)
  • C.\(a\,\text{ln}\left[\frac{(T_{1} + T_{2})^{2}}{4T_{1}T_{2}}\right]\)
  • D.\(a\,\text{ln}\left[\frac{2T_{1}T_{2}}{T_{1} + T_{2}}\right]\)

Answer: A

The entropy change is \(a\Big[2\Big(\frac{T_{1}^{2}+T_{2}^{2}}{2}\Big)^{1/2}-T_{1}-T_{2}\Big]\).

Energy is conserved, so the heat lost by one block equals the heat gained by the other. With \(C = aT\):

\[ \begin{aligned} \int_{T_{1}}^{T_{f}} aT\,dT + \int_{T_{2}}^{T_{f}} aT\,dT &= 0 \\ T_{f} &= \left(\frac{T_{1}^{2} + T_{2}^{2}}{2}\right)^{1/2} \end{aligned} \]

Then \(dS = C\,dT/T = a\,dT\), so each block changes entropy by \(a(T_{f} - T_{i})\):

\[ \Delta S = a(2T_{f} - T_{1} - T_{2}) \]

The ln forms belong to a constant heat capacity, where \(T_{f}\) is the arithmetic mean; they do not apply when C grows with T.

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