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Chlorination of water is most effective at pH ______ because hypochlorous acid is formed at this pH.

  • A.4
  • B.7
  • C.10
  • D.14

Answer: B

Chlorination is most effective at about pH 7.

Chlorine in water forms hypochlorous acid (HOCl), the strongly germicidal form, and the hypochlorite ion (OCl-), which is far weaker. Near neutral pH, around 7, most of the chlorine is present as hypochlorous acid; as the pH rises above about 8 it changes increasingly into hypochlorite and disinfection falls sharply.

pH 10 and 14 are alkaline, where hypochlorite dominates. pH 4 is far too acidic for drinking water. So of the options, pH 7 is the one at which chlorination works best.

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