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Discussion

Consider the following statements about the parameters a and b.
1. Both are determined from the critical temperature and pressure.
2. The parameter b is roughly related to the molecular size.
3. Both are independent of the substance concerned.

  • A.All of them
  • B.1 and 2 only
  • C.3 only
  • D.1 only

Answer: B

The first two are correct. The third is plainly wrong, since the whole purpose of the parameters is to distinguish one substance from another within a single equation form. Their values are tabulated or computed from critical data.

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