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Two identical particles with a fixed total energy \(E = 2\hbar\omega\) are in thermal equilibrium in a one-dimensional harmonic oscillator potential \(\frac{1}{2}m\omega^{2}x^{2}\). Let the entropy of the particles be denoted by \(S_{F}\) if they are fermions with spin \(\frac{1}{2}\) \(\left(s_{z} = \pm\frac{\hbar}{2}\right)\) and \(S_{B}\) if they are bosons with spin 0. Then, which of the following options is correct?

(\(k_{B}\) is the Boltzmann constant)

  • A.\(S_{F} = k_{B} \ln 2, \quad S_{B} = k_{B} \ln 2\)
  • B.\(S_{F} = 2k_{B} \ln 2, \quad S_{B} = 0\)
  • C.\(S_{F} = 4k_{B} \ln 2, \quad S_{B} = 0\)
  • D.\(S_{F} = 2k_{B} \ln 2, \quad S_{B} = k_{B} \ln 2\)

Answer: B

The entropies are \(S_{F} = 2k_{B}\ln 2\) and \(S_{B} = 0\).

The single-particle levels are \((n + \frac{1}{2})\hbar\omega\). Two particles with total energy \(2\hbar\omega\) need \(n_{1} + n_{2} + 1 = 2\), so one particle is in n = 0 and the other in n = 1. The entropy is \(k_{B}\ln\Omega\), where \(\Omega\) counts the distinct many-particle states.

For spin-0 bosons the particles are identical and the occupation {0, 1} is a single state, so \(\Omega = 1\) and \(S_{B} = 0\). For spin-\(\frac{1}{2}\) fermions the two particles are in different levels, so each can have either spin: \(2 \times 2 = 4\) states, and

\[ S_{F} = k_{B}\ln 4 = 2k_{B}\ln 2 \]

Options with \(S_{B} = k_{B}\ln 2\) drop the zero-point energy, which would allow n = (0, 2) and (1, 1) for bosons. \(4k_{B}\ln 2\) would need 16 fermion states.

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