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The kinetic energy of a free electron at a corner of the first Brillouin zone of a two-dimensional square lattice is larger than that of an electron at the midpoint of a side of the zone by a factor b. The value of b is :

  • A.\(b = \sqrt{2}\)
  • B.\(b = 2\)
  • C.\(b = 4\)
  • D.\(b = 8\)

Answer: B

The factor is b = 2.

For a square lattice of side a, the first Brillouin zone is a square with corners at \((\pm\pi/a, \pm\pi/a)\) and side midpoints at \((\pm\pi/a, 0)\) and \((0, \pm\pi/a)\). A free electron's kinetic energy is \(\hbar^{2}k^{2}/2m\), so

\[ \begin{aligned} k_{corner}^{2} &= 2\left(\frac{\pi}{a}\right)^{2} \\ k_{mid}^{2} &= \left(\frac{\pi}{a}\right)^{2} \\ b &= \frac{k_{corner}^{2}}{k_{mid}^{2}} = 2 \end{aligned} \]

\(\sqrt{2}\) is the ratio of the wave vectors, not of the energies; 4 and 8 square that ratio once or twice too often.

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