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On what property does a non-dispersive infrared analyser depend?

  • A.Absorption of infrared radiation by a heteronuclear gas
  • B.Emission of infrared radiation by the heated sample
  • C.Refraction of infrared radiation at the cell windows
  • D.Scattering of infrared radiation by particles in the stream

Answer: A

Carbon monoxide, carbon dioxide, methane and many other gases absorb at characteristic infrared wavelengths because their vibrations change the molecular dipole moment, and the analyser measures how much of a beam survives passage through the sample. Emission would require a hot source in the cell, refraction is not a compositional measurement, and scattering belongs to particulate monitors. The dependence on a changing dipole is also why oxygen, nitrogen and hydrogen are invisible to the technique, which is a limitation and occasionally a convenience.

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