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What is the dead time of a column?

  • A.The delay before the oven reaches its set temperature
  • B.The time an unretained compound takes to pass through
  • C.The interval between injections in a sequence
  • D.The time the detector takes to respond

Answer: B

Dead time is how long the carrier gas itself takes to traverse the column, measured with a compound that does not interact with the stationary phase. Injection intervals, detector response and oven equilibration are other quantities. Because every retention time contains this transit as a floor, subtracting it is what converts a raw time into a measure of how strongly a compound is actually retained. Checking the units of each quantity catches a wrong formula before the arithmetic begins.

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