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Which relationship connects mixing ratio and vapour pressure?

  • A.The mixing ratio is the vapour pressure divided by the total pressure with no further factor applied at all
  • B.The mixing ratio equals the vapour pressure
  • C.The mixing ratio is the total pressure divided by the vapour pressure multiplied by the constant epsilon
  • D.The mixing ratio is epsilon times vapour pressure divided by the difference of total and vapour pressures

Answer: D

The relation \( w = \epsilon e/(p-e) \) follows directly from applying the ideal gas law to each component and taking the ratio of the masses. Because \( e \) is usually small compared with \( p \), the approximation \( w \approx \epsilon e/p \) is often used and is accurate to about one per cent in the lower troposphere. Deriving the exact form once makes the approximation easy to justify when it is needed. Most errors here come from carrying a result across from a neighbouring case where it does not hold.

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