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A reaction may have a 100 per cent yield and still a poor atom economy if

  • A.much of the reactant mass leaves as by-product
  • B.the reaction requires a catalyst
  • C.the product must be purified by distillation
  • D.the reaction is carried out in water

Answer: A

Correct answer: much of the reactant mass leaves as by-product

Yield and atom economy answer different questions. Yield asks how much of the theoretical product was obtained; atom economy asks how much of the reactant mass ends up in that product at all. A reaction that converts every molecule of substrate but sheds most of its mass as a by-product has a perfect yield and a poor atom economy.

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