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Sulphate attack on hardened concrete damages it by

  • A.dissolving away the aggregate particles entirely
  • B.removing all the water from the hardened cement paste
  • C.raising the alkalinity of the pore solution sharply
  • D.forming expansive compounds with the aluminate phase

Answer: D

Correct answer: forming expansive compounds with the aluminate phase

Sulphate reaching the paste reacts with the calcium aluminate hydrates to form ettringite, which occupies a much greater volume than the phases it replaces, so the paste expands and cracks from within. The defences follow from the chemistry: a sulphate-resisting cement low in tricalcium aluminate, or a low permeability that keeps the sulphate out in the first place.

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