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Why is water a poor solvent for infrared but acceptable for Raman?

  • A.Water absorbs strongly in the infrared but scatters weakly
  • B.Water is transparent in the infrared but fluoresces in Raman
  • C.Water dissolves the salt cells used in infrared work
  • D.Water has no vibrations that Raman can detect

Answer: A

Water's hydroxyl bands dominate the infrared spectrum and swamp the sample's, while its Raman scattering is weak and leaves the spectrum clear. It does dissolve salt cells, which is a separate practical nuisance. It certainly has Raman-active vibrations, just weak ones. That one technique tolerates the most important biological solvent and the other does not is a large part of why Raman is used for aqueous and biological samples at all.

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