Machine-translated by Google. Questions are authored in English.
Top

Discussion

Why can a weak band near 3400 be mistaken for a hydroxyl group?

  • A.The instrument's background contributes there
  • B.Water in the sample always absorbs there
  • C.A carbonyl overtone falls in the same region
  • D.Amines absorb at exactly that wavenumber

Answer: C

The first overtone of a carbonyl near 1700 lands close to 3400, where a hydroxyl or amine stretch would also appear, and it is weak enough to be overlooked as an impurity. Amines do absorb nearby, which is a separate confusion, and background and moisture are instrumental rather than intrinsic. Checking whether a weak band is near twice a strong one is the quickest way to rule out an overtone before reporting a functional group.

No comment is present. Be the first to comment.
Loading…

Post your comment

Please log in or register to post a comment.