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A band appears at \( 2350 \ \mathrm{cm^{-1}} \) and varies between scans. What is it?

  • A.An overtone of a carbonyl band
  • B.Atmospheric carbon dioxide
  • C.A nitrile in the sample
  • D.An alkyne in the sample

Answer: B

A band at exactly 2350 that changes between the background and the sample scan is carbon dioxide in the beam path rather than anything in the sample. A nitrile would sit near 2250 and would not vary, an alkyne near 2120, and a carbonyl overtone near 3400. That a band's variability between scans identifies it as atmospheric is a diagnostic no band position alone could provide.

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