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An unknown gives the following bands.

WavenumberAppearance
3300Broad, strong
2950Medium
1050Strong

What is the most likely functional group?

  • A.A ketone
  • B.A nitrile
  • C.An alcohol
  • D.A carboxylic acid

Answer: C

A broad hydroxyl stretch with a strong carbon-oxygen single bond band near 1050 and no carbonyl at all points to an alcohol. An acid would show a carbonyl near 1710 as well, a ketone would show the carbonyl and no hydroxyl, and a nitrile would show a band near 2250. Reading what is absent alongside what is present is what makes this assignment secure rather than merely plausible.

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