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Why is 4 reciprocal centimetres adequate resolution for most routine work?

  • A.The source emits too little for finer resolution
  • B.Finer resolution would exceed the wavelength accuracy
  • C.Solution and solid bands are far wider than that
  • D.The detector cannot respond faster than that

Answer: C

Bands in condensed phases are tens of reciprocal centimetres wide, so resolving to four already describes their shape completely and finer settings only cost time and signal-to-noise. Detector speed, source output and wavelength accuracy are not the binding constraint. A resolution better than the thing being resolved buys nothing, which is the same principle that governs slit width in a dispersive instrument.

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