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The number of shared corners of the constituent SiO4 units in orthosilicate, pyrosilicate, cyclic silicate and sheet silicate, respectively, are

  • A.0, 1, 2 and 3
  • B.2, 3, 0 and 1
  • C.0, 3, 1 and 2
  • D.1, 2, 3 and 0

Answer: A

The numbers of shared corners are 0, 1, 2 and 3.

  • Orthosilicates (SiO44−, e.g. olivine) contain isolated tetrahedra: no shared corners.
  • Pyrosilicates (Si2O76−) join two tetrahedra through one bridging oxygen: one shared corner per tetrahedron.
  • Cyclic silicates (e.g. Si6O1812− in beryl) link tetrahedra in rings, each sharing two corners.
  • Sheet silicates (Si2O52−, e.g. mica, talc) share three corners per tetrahedron in a two-dimensional net.

The other options scramble this sequence; note that three-dimensional silicates such as quartz share all four corners, one more than the sheets.

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